Imports System.Data.OleDb
Public Class Form1
    Private Sub Button1_Click(ByVal sender As System.Object, ByVal e As System.EventArgs) Handles Button1.Click
        Dim connetionString As String
        Dim oledbCnn As OleDbConnection
        Dim oledbCmd As OleDbCommand
        Dim sql As String

        connetionString = "Provider=Microsoft.Jet.OLEDB.4.0;Data Source=Your mdb filename;"
        sql = "Your SQL Statement Here like Select * from product"

        oledbCnn = New OleDbConnection(connetionString)
        Try
            oledbCnn.Open()
            oledbCmd = New OleDbCommand(sql, oledbCnn)
            Dim oledbReader As OleDbDataReader = oledbCmd.ExecuteReader()
            Dim schemaTable As DataTable = oledbReader.GetSchemaTable()
            Dim row As DataRow
            Dim column As DataColumn
            For Each row In schemaTable.Rows
                For Each column In schemaTable.Columns
                    MsgBox(String.Format("{0} = {1}", column.ColumnName, row(column)))
                Next
            Next
            oledbReader.Close()
            oledbCmd.Dispose()
            oledbCnn.Close()
        Catch ex As Exception
            MsgBox("Can not open connection ! ")
        End Try
    End Sub
End Class